Hot oil has typically received the most press, even in this publication. After all, oil is not like fine wines that get better over time. In fact, even the very best wine will stress-out when exposed to too much heat. For instance, most wines will age roughly twice as fast at 77°F compared to 55°F, which is why connoisseurs and collectors prefer cellar temperature to store their liquid assets.

In 1903, Svante Arrhenius won a Nobel Prize when he figured out the relationship between temperature and most chemical reaction rates. Often called the Arrhenius Rate Rule, it relates to the fact that lubricants, once they’ve exceeded their base activation temperature, will degrade or oxidize twice as fast for every 10°C (18°F) increase in temperature.

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There has been much said in recent years about the increased propensity of some modern oil formulations to produce sludge and varnish. Ironically, many of the oils accused of contributing to varnish are the same oils endowed with exceptionally high oxidation stability due to advanced refining technology and formulation science. To better understand this paradox, let’s begin by defining a new term.Lubricants have an intrinsic Impurity- holding Capacity (IHC) relating to their ability to retain very small (submicron) impurities in solution. These impurities are largely oil-degradation products, but include other oil suspensions as well.

This holding capacity is like an imaginary silo or cup within the oil. If the cup is half empty, it has unutilized or reserve capacity. However, conditions can occur that can cause an overfill, leading to insoluble suspensions in the oil and varnish (sometimes called the “dumping point”).

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