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	<title>Bulk thermal degradation Archives | Tesibis</title>
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	<description>Consulting &#38; Expert Testimony on Lubrication &#38; Oil Analysis</description>
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	<title>Bulk thermal degradation Archives | Tesibis</title>
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		<title>Review of Degradation Mechanisms Leading to Sludge and Varnish in Modern Turbine Oil Formulations</title>
		<link>https://tesibis.com/sludge-and-varnish/2-review-of-degradation-mechanisms-leading-to-sludge-and-varnish-in-modern-turbine-oil-formulations/</link>
		
		<dc:creator><![CDATA[Jim Fitch]]></dc:creator>
		<pubDate>Thu, 18 Dec 2025 15:26:25 +0000</pubDate>
				<category><![CDATA[Sludge & Varnish]]></category>
		<category><![CDATA[Aeration of the fluid]]></category>
		<category><![CDATA[Antifreeze contamination]]></category>
		<category><![CDATA[Bulk oil oxidation]]></category>
		<category><![CDATA[Bulk thermal degradation]]></category>
		<category><![CDATA[hydrolysis]]></category>
		<category><![CDATA[microdieseling]]></category>
		<category><![CDATA[Soot coagulation]]></category>
		<category><![CDATA[Sparking from static electricity]]></category>
		<guid isPermaLink="false">https://tesibis.com/?p=1106</guid>

					<description><![CDATA[<p>In recent years, there has been an unusually large number of reported cases associated with varnish and sludge formation in turbine-generator and compressor applications using Group II turbine oil formulations.</p>
<p>The post <a href="https://tesibis.com/sludge-and-varnish/2-review-of-degradation-mechanisms-leading-to-sludge-and-varnish-in-modern-turbine-oil-formulations/">Review of Degradation Mechanisms Leading to Sludge and Varnish in Modern Turbine Oil Formulations</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
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										<content:encoded><![CDATA[
<p class="wp-block-paragraph">By Jim Fitch and Sabrin Gebarin<br>Journal of ASTM International, Vol.3, No. 8</p>



<figure class="wp-block-image size-full"><img fetchpriority="high" decoding="async" width="468" height="137" src="https://tesibis.com/wp-content/uploads/2025/12/image-147.png" alt="" class="wp-image-1107" srcset="https://tesibis.com/wp-content/uploads/2025/12/image-147.png 468w, https://tesibis.com/wp-content/uploads/2025/12/image-147-300x88.png 300w" sizes="(max-width: 468px) 100vw, 468px" /></figure>



<p class="wp-block-paragraph">In recent years, there has been an unusually large number of reported cases associated with varnish and sludge formation in turbine-generator and compressor applications using Group II turbine oil formulations. Explanations for these problems have varied but typically include Group I/Group II incompatibility, additive instability, bulk oil oxidation, adiabatic compressive heating, electrostatic discharge, among others. This paper reviews these failure pathways and discusses actual case history including root cause analysis. Analytical methods for the sludge/varnish and the degraded oll are also reviewed.</p>



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<div class="wp-block-button is-style-tesibis-outline-blue-blue"><a class="wp-block-button__link wp-element-button" href="https://tesibis.com/pdf/articles/Review-of-Degradation-Mechanisms-Leading-to-Sludge-and-Varnish-in-Modern-Turbine-Oil-Formulations.pdf" target="_blank" rel="noreferrer noopener">Read the full paper</a></div>
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<p>The post <a href="https://tesibis.com/sludge-and-varnish/2-review-of-degradation-mechanisms-leading-to-sludge-and-varnish-in-modern-turbine-oil-formulations/">Review of Degradation Mechanisms Leading to Sludge and Varnish in Modern Turbine Oil Formulations</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
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			</item>
		<item>
		<title>Sludge and Varnish: Two Puzzling Contaminants</title>
		<link>https://tesibis.com/sludge-and-varnish/2-sludge-and-varnish-two-puzzling-contaminants/</link>
		
		<dc:creator><![CDATA[Jim Fitch]]></dc:creator>
		<pubDate>Thu, 18 Dec 2025 15:20:42 +0000</pubDate>
				<category><![CDATA[Sludge & Varnish]]></category>
		<category><![CDATA[Aeration of the fluid]]></category>
		<category><![CDATA[Antifreeze contamination]]></category>
		<category><![CDATA[Bulk oil oxidation]]></category>
		<category><![CDATA[Bulk thermal degradation]]></category>
		<category><![CDATA[hydrolysis]]></category>
		<category><![CDATA[microdieseling]]></category>
		<category><![CDATA[Soot coagulation]]></category>
		<category><![CDATA[Sparking from static electricity]]></category>
		<guid isPermaLink="false">https://tesibis.com/?p=1103</guid>

					<description><![CDATA[<p>Most oil-related problems in machinery lead to wear or corrosion. However, there is one very serious problem - the presence of sludge and varnish – that may cause neither. Instead, these substances plug flow passages and cause valve sticking.</p>
<p>The post <a href="https://tesibis.com/sludge-and-varnish/2-sludge-and-varnish-two-puzzling-contaminants/">Sludge and Varnish: Two Puzzling Contaminants</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
]]></description>
										<content:encoded><![CDATA[
<p class="wp-block-paragraph">By Jim Fitch<br>Hydraulics &amp; Pneumatics Magazine</p>



<p class="wp-block-paragraph">Most oil-related problems in machinery lead to wear or corrosion. However, there is one very serious problem &#8211; the presence of sludge and varnish – that may cause neither. Instead, these substances plug flow passages and cause valve sticking. Sludge and varnish can occur even In the most well maintained machines. Surprisingly, they may also appear when oils are not particularly old or contaminated. And they can occur in even though most thermally robust synthetic hydraulic fluids. While there a:re many well-known reasons why oils will throw sludge, there are an equal number that are unknown or misunderstood. </p>



<p class="wp-block-paragraph">First, what is the distinction between varnish and sludge? Both can form directly or through n sequence of intermediate steps. For simplify lion, we will define varnish as tough, adherent oxide or carbonaceous material that coats internal machine surfaces. Heat and/or time will cure varnish to a hard, brittle consistency. On the other hand, sludge, which is sometimes a precursor to varnish, is soft and sticky in form. Sludge can move around a system until it finally comes to rest at sump bottoms, troughs, strainers, filters, and narrow fluid passages. Other common names for varnish and sludge include deposits, lacquer, tars, pigments, gums, and resins.</p>



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<p>The post <a href="https://tesibis.com/sludge-and-varnish/2-sludge-and-varnish-two-puzzling-contaminants/">Sludge and Varnish: Two Puzzling Contaminants</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
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