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	<title>oxidation Archives | Tesibis</title>
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	<description>Consulting &#38; Expert Testimony on Lubrication &#38; Oil Analysis</description>
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	<title>oxidation Archives | Tesibis</title>
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		<title>Advancements in Fluid Analysis Technologies and Strategies for Hydraulic SystemCondition-Based Maintenance</title>
		<link>https://tesibis.com/condition-monitoring/1-advancements-in-fluid-analysis-technologies-and-strategies-for-hydraulic-systemcondition-based-maintenance/</link>
		
		<dc:creator><![CDATA[Jim Fitch]]></dc:creator>
		<pubDate>Tue, 16 Dec 2025 21:42:53 +0000</pubDate>
				<category><![CDATA[Condition Monitoring]]></category>
		<category><![CDATA[additives]]></category>
		<category><![CDATA[analytical ferrography]]></category>
		<category><![CDATA[contamination]]></category>
		<category><![CDATA[ferrous density analysis]]></category>
		<category><![CDATA[moisture]]></category>
		<category><![CDATA[oil analysis]]></category>
		<category><![CDATA[oil properties]]></category>
		<category><![CDATA[oil sampling]]></category>
		<category><![CDATA[oxidation]]></category>
		<category><![CDATA[Particles]]></category>
		<category><![CDATA[spectroscopy]]></category>
		<category><![CDATA[thermal stability]]></category>
		<category><![CDATA[varnish]]></category>
		<category><![CDATA[viscosity]]></category>
		<category><![CDATA[wear debris]]></category>
		<guid isPermaLink="false">https://tesibis.com/?p=758</guid>

					<description><![CDATA[<p>World-class condition monitoring of hydraulic systems involves the successful integration of a number of strategic elements. While in the past, walk-around inspections and gage data were the primary means of monitoring system health, today's modem oil analysis programs apply a host of sophisticated new tools and instruments.</p>
<p>The post <a href="https://tesibis.com/condition-monitoring/1-advancements-in-fluid-analysis-technologies-and-strategies-for-hydraulic-systemcondition-based-maintenance/">Advancements in Fluid Analysis Technologies and Strategies for Hydraulic SystemCondition-Based Maintenance</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
]]></description>
										<content:encoded><![CDATA[
<p class="wp-block-paragraph">By Jim Fitch<br>Book chapter.&nbsp; <strong>Hydraulic Failure Analysis: Fluids, Components and System Effects, </strong>by George Totten et al</p>



<figure class="wp-block-image size-full"><img fetchpriority="high" decoding="async" width="308" height="223" src="https://tesibis.com/wp-content/uploads/2025/12/image-66.png" alt="" class="wp-image-759" srcset="https://tesibis.com/wp-content/uploads/2025/12/image-66.png 308w, https://tesibis.com/wp-content/uploads/2025/12/image-66-300x217.png 300w" sizes="(max-width: 308px) 100vw, 308px" /></figure>



<p class="wp-block-paragraph">World-class condition monitoring of hydraulic systems involves the successful integration of a number of strategic elements. While in the past, walk-around inspections and gage data were the primary means of monitoring system health, today&#8217;s modem oil analysis programs apply a host of sophisticated new tools and instruments. Reliability teams at the plant site frequently commission small laboratories. In many cases the instrumentation suite includes portable and unattended sensors. The situational context is changing too as today&#8217;s hydraulic systems are increasingly designed for higher pressures, speeds, and temperatures. This paper presents a review of strategic elements that, when well conceived and implemented, can deliver vital aiding information for achieving even the toughest condition-based maintenance goals. These include the selection of test slate, deployment of incipient failure advisories, setting of targets and limits that define nonconforming conditions, exception testing, and proactive maintenance.</p>



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<p>The post <a href="https://tesibis.com/condition-monitoring/1-advancements-in-fluid-analysis-technologies-and-strategies-for-hydraulic-systemcondition-based-maintenance/">Advancements in Fluid Analysis Technologies and Strategies for Hydraulic SystemCondition-Based Maintenance</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
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		<title>Five Ways Aerated Oil Wrecks Machines</title>
		<link>https://tesibis.com/water-air-contamination/1-five-ways-aerated-oil-wrecks-machines/</link>
		
		<dc:creator><![CDATA[Jim Fitch]]></dc:creator>
		<pubDate>Thu, 18 Dec 2025 17:32:01 +0000</pubDate>
				<category><![CDATA[Water & Air Contamination]]></category>
		<category><![CDATA[Aeration]]></category>
		<category><![CDATA[air entrainment]]></category>
		<category><![CDATA[air release]]></category>
		<category><![CDATA[cavitation]]></category>
		<category><![CDATA[detrainment]]></category>
		<category><![CDATA[dissolved air]]></category>
		<category><![CDATA[foam]]></category>
		<category><![CDATA[free air]]></category>
		<category><![CDATA[froth]]></category>
		<category><![CDATA[oxidation]]></category>
		<guid isPermaLink="false">https://tesibis.com/?p=1113</guid>

					<description><![CDATA[<p>We’re told machines should not be allowed to swallow air. But what if they do?  What harm could be caused by this bubbly stuff anyway? Do we really have to make the machine burp?</p>
<p>The post <a href="https://tesibis.com/water-air-contamination/1-five-ways-aerated-oil-wrecks-machines/">Five Ways Aerated Oil Wrecks Machines</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
]]></description>
										<content:encoded><![CDATA[
<p class="wp-block-paragraph">By Jim Fitch<br>Practicing Oil Analysis Magazine</p>



<figure class="wp-block-image size-full"><img decoding="async" width="170" height="173" src="https://tesibis.com/wp-content/uploads/2025/12/image-149.png" alt="" class="wp-image-1114"/></figure>



<p class="wp-block-paragraph">We’re told machines should not be allowed to swallow air. But what if they do?  What harm could be caused by this bubbly stuff anyway? Do we really have to make the machine burp? Will a few pats on the back do the trick?  For many of you, air contamination is no laughing matter. Why? Because air contamination is a serious condition.  There are five deadly problems associated with aerated oil. By aerated oil, I’m referring to entrained air, foam or both, which is the usual case.</p>



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<p>The post <a href="https://tesibis.com/water-air-contamination/1-five-ways-aerated-oil-wrecks-machines/">Five Ways Aerated Oil Wrecks Machines</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
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		<title>The Four States of Water in Oil</title>
		<link>https://tesibis.com/water-air-contamination/1-the-four-states-of-water-in-oil/</link>
		
		<dc:creator><![CDATA[Jim Fitch]]></dc:creator>
		<pubDate>Thu, 18 Dec 2025 17:57:09 +0000</pubDate>
				<category><![CDATA[Water & Air Contamination]]></category>
		<category><![CDATA[additive depletion]]></category>
		<category><![CDATA[corrosion]]></category>
		<category><![CDATA[dew point]]></category>
		<category><![CDATA[dissolved water]]></category>
		<category><![CDATA[emulsified water]]></category>
		<category><![CDATA[free water]]></category>
		<category><![CDATA[hydrolysis]]></category>
		<category><![CDATA[hydrolytic stability]]></category>
		<category><![CDATA[oxidation]]></category>
		<category><![CDATA[saturation point]]></category>
		<category><![CDATA[water handles]]></category>
		<category><![CDATA[water mopping]]></category>
		<guid isPermaLink="false">https://tesibis.com/?p=1137</guid>

					<description><![CDATA[<p>In the last 30 years or so, most of the literature, including Noria’s publications, refer to water as having three states. Free water has been redefined as being water that, by force of gravity, will phase out of the oil. This means it will separate below (most common) or above the oil phase depending on oil density.</p>
<p>The post <a href="https://tesibis.com/water-air-contamination/1-the-four-states-of-water-in-oil/">The Four States of Water in Oil</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
]]></description>
										<content:encoded><![CDATA[
<p class="wp-block-paragraph">By Jim Fitch<br>Machinery Lubrication Magazine</p>



<figure class="wp-block-image size-full"><img decoding="async" width="188" height="296" src="https://tesibis.com/wp-content/uploads/2025/12/image-155.png" alt="" class="wp-image-1138"/></figure>



<p class="wp-block-paragraph">Historically, water contaminated oil has been said to exist in two states:</p>



<ul class="wp-block-list">
<li>Dissolved water (bound molecularly in the matrix of the oil)</li>



<li>Free water (not molecularly bound)</li>
</ul>



<p class="wp-block-paragraph">In the last 30 years or so, most of the literature, including Noria’s publications, refer to water as having three states. Free water has been redefined as being water that, by force of gravity, will phase out of the oil. This means it will separate below (most common) or above the oil phase depending on oil density.</p>



<p class="wp-block-paragraph">The new third state is emulsified water. Water that is held tightly in micro-globules in the oil is no longer referred to as free water. Instead, it has been more accurately referred to as emulsified water, or a &#8220;micro-emulsion&#8221;.</p>



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<p>The post <a href="https://tesibis.com/water-air-contamination/1-the-four-states-of-water-in-oil/">The Four States of Water in Oil</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
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		<title>Diagnosing a Cloudy Oil</title>
		<link>https://tesibis.com/inspection/2-diagnosing-a-cloudy-oil/</link>
		
		<dc:creator><![CDATA[Jim Fitch]]></dc:creator>
		<pubDate>Wed, 17 Dec 2025 17:44:04 +0000</pubDate>
				<category><![CDATA[Inspection]]></category>
		<category><![CDATA[Aeration]]></category>
		<category><![CDATA[cross contamination]]></category>
		<category><![CDATA[dead additives]]></category>
		<category><![CDATA[incompatibility]]></category>
		<category><![CDATA[insolubles]]></category>
		<category><![CDATA[oxidation]]></category>
		<category><![CDATA[salt]]></category>
		<category><![CDATA[undissolved additives]]></category>
		<category><![CDATA[water emulsion]]></category>
		<category><![CDATA[wax]]></category>
		<guid isPermaLink="false">https://tesibis.com/?p=867</guid>

					<description><![CDATA[<p>Most of us know that healthy lubricants are generally clear and bright. However, as oils age they can lose their luster, and many become dark and opaque. These optical changes are often important symptoms of impending problems that, if occur prematurely, merit further analysis and corrective action.</p>
<p>The post <a href="https://tesibis.com/inspection/2-diagnosing-a-cloudy-oil/">Diagnosing a Cloudy Oil</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
]]></description>
										<content:encoded><![CDATA[
<p class="wp-block-paragraph">By Jim Fitch<br>Practicing Oil Analysis Magazine</p>



<p class="wp-block-paragraph">Most of us know that healthy lubricants are generally clear and bright. However, as oils age they can lose their luster, and many become dark and opaque. These optical changes are often important symptoms of impending problems that, if occur prematurely, merit further analysis and corrective action.</p>



<p class="wp-block-paragraph">However, in other cases they can be benign or simply the result of the oil&#8217;s normal aging process. So how do we know the difference, especially without having to perform complex laboratory analysis? Like much in the field of oil analysis, answering such questions depends first on better understanding the nature of the problem.</p>



<p class="wp-block-paragraph">We can score an oil visually the same way gemologists grade diamonds; by color and clarity. An oil&#8217;s luster or brightness is influenced by both of these options.</p>



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<p>The post <a href="https://tesibis.com/inspection/2-diagnosing-a-cloudy-oil/">Diagnosing a Cloudy Oil</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
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		<title>How Water Causes Bearing Failure</title>
		<link>https://tesibis.com/gears-and-bearings-lubrication/2-how-water-causes-bearing-failure/</link>
		
		<dc:creator><![CDATA[Jim Fitch]]></dc:creator>
		<pubDate>Mon, 22 Dec 2025 23:10:42 +0000</pubDate>
				<category><![CDATA[Gears & Bearings Lubrication]]></category>
		<category><![CDATA[additive depletion]]></category>
		<category><![CDATA[Aeration]]></category>
		<category><![CDATA[corrosion]]></category>
		<category><![CDATA[film strength]]></category>
		<category><![CDATA[foam]]></category>
		<category><![CDATA[hydrogen-induced fractures]]></category>
		<category><![CDATA[hydrolysis]]></category>
		<category><![CDATA[microbial contamination]]></category>
		<category><![CDATA[oxidation]]></category>
		<category><![CDATA[water washing]]></category>
		<guid isPermaLink="false">https://tesibis.com/?p=1350</guid>

					<description><![CDATA[<p>By Jim FitchMachinery Lubrication Magazine It takes only a small amount of water (less than 500 ppm) to substantially shorten the service life of rolling element bearings. There is a vast amount of research that supports this. Being a career-long crusader of clean and dry oil, I will certainly not argue the contrary. In fact, [&#8230;]</p>
<p>The post <a href="https://tesibis.com/gears-and-bearings-lubrication/2-how-water-causes-bearing-failure/">How Water Causes Bearing Failure</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
]]></description>
										<content:encoded><![CDATA[
<p class="wp-block-paragraph">By Jim Fitch<br>Machinery Lubrication Magazine</p>



<figure class="wp-block-image size-full"><img loading="lazy" decoding="async" width="680" height="383" src="https://tesibis.com/wp-content/uploads/2025/12/image-179.png" alt="" class="wp-image-1351" srcset="https://tesibis.com/wp-content/uploads/2025/12/image-179.png 680w, https://tesibis.com/wp-content/uploads/2025/12/image-179-300x169.png 300w" sizes="auto, (max-width: 680px) 100vw, 680px" /></figure>



<p class="wp-block-paragraph">It takes only a small amount of water (less than 500 ppm) to substantially shorten the service life of rolling element bearings. There is a vast amount of research that supports this. Being a career-long crusader of clean and dry oil, I will certainly not argue the contrary. In fact, water&#8217;s destructive effects on bearings can easily reach or exceed that of particle contamination, depending on the conditions.</p>



<p class="wp-block-paragraph">My theme for this column, therefore, is not about whether water imparts harm but rather how it does. Knowing how water attacks and causes damage helps in setting important dryness targets and also aids failure investigations post mortem. Further, when water contamination is unavoidable, understanding these water-induced failure modes can be valuable in the optimum selection of lubricants, bearings and seals for defensive purposes.</p>



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<p>The post <a href="https://tesibis.com/gears-and-bearings-lubrication/2-how-water-causes-bearing-failure/">How Water Causes Bearing Failure</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
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		<title>The Hazards of Water Contamination in Oil</title>
		<link>https://tesibis.com/water-air-contamination/2-the-hazards-of-water-contamination-in-oil/</link>
		
		<dc:creator><![CDATA[Jim Fitch]]></dc:creator>
		<pubDate>Wed, 17 Dec 2025 16:30:18 +0000</pubDate>
				<category><![CDATA[Water & Air Contamination]]></category>
		<category><![CDATA[hydrolysis]]></category>
		<category><![CDATA[moisture contamination]]></category>
		<category><![CDATA[oil-water emulsion]]></category>
		<category><![CDATA[oxidation]]></category>
		<category><![CDATA[water contamination]]></category>
		<category><![CDATA[water-induced failure]]></category>
		<guid isPermaLink="false">https://tesibis.com/?p=782</guid>

					<description><![CDATA[<p>Most of us are well aware of the enormous damage water can exact on a machine and its lubricants. However, the magnitude of this potential destruction seems to depend directly on five enabling factors. These factors are listed below and are further diagramed in Figure 1.</p>
<p>The post <a href="https://tesibis.com/water-air-contamination/2-the-hazards-of-water-contamination-in-oil/">The Hazards of Water Contamination in Oil</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
]]></description>
										<content:encoded><![CDATA[
<p class="wp-block-paragraph">By Jim Fitch<br>Practicing Oil Analysis Magazine</p>



<figure class="wp-block-image size-full"><img loading="lazy" decoding="async" width="700" height="511" src="https://tesibis.com/wp-content/uploads/2025/12/image-71.png" alt="" class="wp-image-783" srcset="https://tesibis.com/wp-content/uploads/2025/12/image-71.png 700w, https://tesibis.com/wp-content/uploads/2025/12/image-71-300x219.png 300w" sizes="auto, (max-width: 700px) 100vw, 700px" /></figure>



<p class="wp-block-paragraph"><br>Most of us are well aware of the enormous damage water can exact on a machine and its lubricants. However, the magnitude of this potential destruction seems to depend directly on five enabling factors. These factors are listed below and are further diagramed in Figure 1.</p>



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<p>The post <a href="https://tesibis.com/water-air-contamination/2-the-hazards-of-water-contamination-in-oil/">The Hazards of Water Contamination in Oil</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
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