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	<title>thermal degradation Archives | Tesibis</title>
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	<description>Consulting &#38; Expert Testimony on Lubrication &#38; Oil Analysis</description>
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	<title>thermal degradation Archives | Tesibis</title>
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	<item>
		<title>Demystifying Sludge and Varnish</title>
		<link>https://tesibis.com/sludge-and-varnish/1-demystifying-sludge-and-varnish/</link>
		
		<dc:creator><![CDATA[Jim Fitch]]></dc:creator>
		<pubDate>Thu, 18 Dec 2025 15:17:46 +0000</pubDate>
				<category><![CDATA[Sludge & Varnish]]></category>
		<category><![CDATA[Additive incompatibilities]]></category>
		<category><![CDATA[Aeration]]></category>
		<category><![CDATA[Antifreeze contamination]]></category>
		<category><![CDATA[Base oil incompatibilities]]></category>
		<category><![CDATA[Black deposits]]></category>
		<category><![CDATA[black enamel]]></category>
		<category><![CDATA[Black scabby deposits]]></category>
		<category><![CDATA[Carbonaceous residue]]></category>
		<category><![CDATA[Caustic detergent contamination]]></category>
		<category><![CDATA[Charcoal deposits]]></category>
		<category><![CDATA[Coking]]></category>
		<category><![CDATA[cold storage]]></category>
		<category><![CDATA[Gold films]]></category>
		<category><![CDATA[Gooey-brown mayonnaise]]></category>
		<category><![CDATA[Grease contaminated oil]]></category>
		<category><![CDATA[gummy deposits]]></category>
		<category><![CDATA[gunk]]></category>
		<category><![CDATA[Highly aromatic fuels]]></category>
		<category><![CDATA[hydrolysis]]></category>
		<category><![CDATA[Lead corrosion reactions]]></category>
		<category><![CDATA[Lumpy globs]]></category>
		<category><![CDATA[Nitration]]></category>
		<category><![CDATA[oil oxidation]]></category>
		<category><![CDATA[Poor combustion]]></category>
		<category><![CDATA[radiological contamination]]></category>
		<category><![CDATA[Reactive compressor gases]]></category>
		<category><![CDATA[slime]]></category>
		<category><![CDATA[Soot coagulation]]></category>
		<category><![CDATA[Sparking]]></category>
		<category><![CDATA[Sulfation]]></category>
		<category><![CDATA[thermal degradation]]></category>
		<guid isPermaLink="false">https://tesibis.com/?p=1100</guid>

					<description><![CDATA[<p>The approach of detecting and analyzing sludge and varnish problems in machinery is not the same as used oil analysis. In many instances this is because the evidence is not always in the oil. </p>
<p>The post <a href="https://tesibis.com/sludge-and-varnish/1-demystifying-sludge-and-varnish/">Demystifying Sludge and Varnish</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
]]></description>
										<content:encoded><![CDATA[
<p class="wp-block-paragraph">By Jim Fitch<br>Machinery Lubrication Magazine</p>



<figure class="wp-block-image size-full"><img decoding="async" width="180" height="155" src="https://tesibis.com/wp-content/uploads/2025/12/image-146.png" alt="" class="wp-image-1101"/></figure>



<p class="wp-block-paragraph">The approach of detecting and analyzing sludge and varnish problems in machinery is not the same as used oil analysis. In many instances this is because the evidence is not always in the oil. The sludge and varnish should be analyzed directly, using a completely different set of tests and evaluation parameters. Still, used oil analysis plays an important diagnostic role to help reveal candidate causes as well as to rule-out others.</p>



<p class="wp-block-paragraph">The conditions that commonly lead to sludge and varnish problems vary, which complicates the process of identifying the root cause analytically. There are at least 25 unique lubricant degradation mechanisms leading to sludge or varnish formation.</p>



<div class="wp-block-buttons is-layout-flex wp-block-buttons-is-layout-flex">
<div class="wp-block-button is-style-tesibis-outline-blue-blue"><a class="wp-block-button__link wp-element-button" href="https://www.machinerylubrication.com/Read/268/oil-sludge-varnish" target="_blank" rel="noreferrer noopener">Read the full article</a></div>
</div>
<p>The post <a href="https://tesibis.com/sludge-and-varnish/1-demystifying-sludge-and-varnish/">Demystifying Sludge and Varnish</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
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		<title>Review of Degradation Mechanisms Leading to Sludge and Varnish in Modem Turbine Oil Formulations</title>
		<link>https://tesibis.com/lubricant-analysis/1-review-of-degradation-mechanisms-leading-to-sludge-and-varnish-in-modem-turbine-oil-formulations/</link>
		
		<dc:creator><![CDATA[Jim Fitch]]></dc:creator>
		<pubDate>Tue, 16 Dec 2025 15:10:16 +0000</pubDate>
				<category><![CDATA[Lubricant Analysis]]></category>
		<category><![CDATA[deposits]]></category>
		<category><![CDATA[oil aging]]></category>
		<category><![CDATA[oil analysis]]></category>
		<category><![CDATA[oil change interval]]></category>
		<category><![CDATA[oil degradation]]></category>
		<category><![CDATA[oil oxidation]]></category>
		<category><![CDATA[oxidation insolubles]]></category>
		<category><![CDATA[R&O oil]]></category>
		<category><![CDATA[thermal degradation]]></category>
		<category><![CDATA[turbine oil]]></category>
		<category><![CDATA[varnish]]></category>
		<guid isPermaLink="false">https://tesibis.com/?p=562</guid>

					<description><![CDATA[<p>A wide range of fluid degradation and contamination-related issues can affect turbine lube oil systems. One serious and growing concern is the presence of sludge and varnish. </p>
<p>The post <a href="https://tesibis.com/lubricant-analysis/1-review-of-degradation-mechanisms-leading-to-sludge-and-varnish-in-modem-turbine-oil-formulations/">Review of Degradation Mechanisms Leading to Sludge and Varnish in Modem Turbine Oil Formulations</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
]]></description>
										<content:encoded><![CDATA[
<p class="wp-block-paragraph">By Jim Fitch and Sabrin Gebarin<br>Proceedings of the Oxidation and Testing of Turbine Oils Symposium</p>



<figure class="wp-block-image size-full"><img fetchpriority="high" decoding="async" width="468" height="148" src="https://tesibis.com/wp-content/uploads/2025/12/image-23.png" alt="" class="wp-image-563" srcset="https://tesibis.com/wp-content/uploads/2025/12/image-23.png 468w, https://tesibis.com/wp-content/uploads/2025/12/image-23-300x95.png 300w" sizes="(max-width: 468px) 100vw, 468px" /></figure>



<p class="wp-block-paragraph">A wide range of fluid degradation and contamination-related issues can affect turbine lube oil systems. One serious and growing concern is the presence of sludge and varnish. This condition can occur in even the most well-maintained machines. Surprisingly, it can also happen when oils are not particularly old or contaminated. And it can occur with even the most thermally robust synthetic lubricants and hydraulic fluids.</p>



<p class="wp-block-paragraph">In turbine systems, there are few failure conditions that can disrupt operation as quickly and completely as a varnished and seized-up control valve operation. This can be the cause of a tripped turbine forced outage or other production losses. So too, sludge in many circulating lube oil systems can gum up flow controls, strainers and critical oil ways. In recent years, there has been a large number of reported cases associated with varnish and sludge formation in turbine-generator applications. Explanations for these problems have varied but typically include Group II mineral oil solubility issues, additive instability, bulk oil oxidation, adiabatic compressive heating and electrostatic discharge, among others. This paper will review precursor conditions that lead to sludge formation, some of the common lubricant degradation methods and the role of oil analysis in recognizing the potential risk well ahead of failure.</p>



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<div class="wp-block-button is-style-tesibis-outline-blue-blue"><a class="wp-block-button__link wp-element-button" href="https://tesibis.com/pdf/articles/Oxidation-and-Testing-of-Turbine-Oils-Symposium.pdf" target="_blank" rel="noreferrer noopener">Read the full article</a></div>
</div>
<p>The post <a href="https://tesibis.com/lubricant-analysis/1-review-of-degradation-mechanisms-leading-to-sludge-and-varnish-in-modem-turbine-oil-formulations/">Review of Degradation Mechanisms Leading to Sludge and Varnish in Modem Turbine Oil Formulations</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
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		<title>The Effects of Temperature on Lubricants (Why oil is like an egg)</title>
		<link>https://tesibis.com/sludge-and-varnish/1-the-effects-of-temperature-on-lubricants-why-oil-is-like-an-egg/</link>
		
		<dc:creator><![CDATA[Jim Fitch]]></dc:creator>
		<pubDate>Thu, 18 Dec 2025 15:27:53 +0000</pubDate>
				<category><![CDATA[Sludge & Varnish]]></category>
		<category><![CDATA[additive precipitation]]></category>
		<category><![CDATA[Arrhenius]]></category>
		<category><![CDATA[oxidative degradation]]></category>
		<category><![CDATA[thermal degradation]]></category>
		<category><![CDATA[thermal stability]]></category>
		<category><![CDATA[wax]]></category>
		<guid isPermaLink="false">https://tesibis.com/?p=1109</guid>

					<description><![CDATA[<p>Hot oil has typically received the most press, even in this publication. After all, oil is not like fine wines that get better over time. In fact, even the very best wine will stress-out when exposed to too much heat. </p>
<p>The post <a href="https://tesibis.com/sludge-and-varnish/1-the-effects-of-temperature-on-lubricants-why-oil-is-like-an-egg/">The Effects of Temperature on Lubricants (Why oil is like an egg)</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
]]></description>
										<content:encoded><![CDATA[
<p class="wp-block-paragraph">By Jim Fitch<br>Practicing Oil Analysis Magazine</p>



<figure class="wp-block-image size-full"><img decoding="async" width="299" height="168" src="https://tesibis.com/wp-content/uploads/2025/12/image-148.png" alt="" class="wp-image-1110"/></figure>



<p class="wp-block-paragraph">Hot oil has typically received the most press, even in this publication. After all, oil is not like fine wines that get better over time. In fact, even the very best wine will stress-out when exposed to too much heat. For instance, most wines will age roughly twice as fast at 77°F compared to 55°F, which is why connoisseurs and collectors prefer cellar temperature to store their liquid assets.</p>



<p class="wp-block-paragraph">In 1903, Svante Arrhenius won a Nobel Prize when he figured out the relationship between temperature and most chemical reaction rates. Often called the Arrhenius Rate Rule, it relates to the fact that lubricants, once they&#8217;ve exceeded their base activation temperature, will degrade or oxidize twice as fast for every 10°C (18°F) increase in temperature.</p>



<div class="wp-block-buttons is-layout-flex wp-block-buttons-is-layout-flex">
<div class="wp-block-button is-style-tesibis-outline-blue-blue"><a class="wp-block-button__link wp-element-button" href="https://www.machinerylubrication.com/Read/993/oil-egg" target="_blank" rel="noreferrer noopener">Read the full article</a></div>
</div>
<p>The post <a href="https://tesibis.com/sludge-and-varnish/1-the-effects-of-temperature-on-lubricants-why-oil-is-like-an-egg/">The Effects of Temperature on Lubricants (Why oil is like an egg)</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
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		<title>Be Alert to Heat as Both a Contaminant and a Symptom</title>
		<link>https://tesibis.com/rca-and-failure-analysis/2-be-alert-to-heat-as-both-a-contaminant-and-a-symptom/</link>
		
		<dc:creator><![CDATA[Jim Fitch]]></dc:creator>
		<pubDate>Thu, 18 Dec 2025 14:50:30 +0000</pubDate>
				<category><![CDATA[RCA & Failure Analysis]]></category>
		<category><![CDATA[heat monitoring]]></category>
		<category><![CDATA[hot spots]]></category>
		<category><![CDATA[hot-running machines]]></category>
		<category><![CDATA[infrared analysis]]></category>
		<category><![CDATA[infrared imaging]]></category>
		<category><![CDATA[infrared thermography]]></category>
		<category><![CDATA[temperature inspections]]></category>
		<category><![CDATA[thermal degradation]]></category>
		<category><![CDATA[thermal excursion]]></category>
		<category><![CDATA[thermal runaway]]></category>
		<category><![CDATA[thermography]]></category>
		<guid isPermaLink="false">https://tesibis.com/?p=1084</guid>

					<description><![CDATA[<p>Excessive heat is a severe contaminant. It wreaks havoc on oil (chemically and physically) and retards lubricant performance by increasing wear, corrosion and friction. Friction and wear cause more heat, which sends the machine into a cycle of despair.</p>
<p>The post <a href="https://tesibis.com/rca-and-failure-analysis/2-be-alert-to-heat-as-both-a-contaminant-and-a-symptom/">Be Alert to Heat as Both a Contaminant and a Symptom</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
]]></description>
										<content:encoded><![CDATA[
<p class="wp-block-paragraph">By Jim Fitch<br>Machinery Lubrication Magazine</p>



<figure class="wp-block-image size-full"><img loading="lazy" decoding="async" width="375" height="72" src="https://tesibis.com/wp-content/uploads/2025/12/image-141.png" alt="" class="wp-image-1085" srcset="https://tesibis.com/wp-content/uploads/2025/12/image-141.png 375w, https://tesibis.com/wp-content/uploads/2025/12/image-141-300x58.png 300w" sizes="auto, (max-width: 375px) 100vw, 375px" /></figure>



<p class="wp-block-paragraph">Excessive heat is a severe contaminant. It wreaks havoc on oil (chemically and physically) and retards lubricant performance by increasing wear, corrosion and friction. Friction and wear cause more heat, which sends the machine into a cycle of despair.</p>



<p class="wp-block-paragraph">Heat must be controlled within the machine’s operating limits. This varies considerably between machine types and applications. Lubricants have their own unique limits as well.</p>



<p class="wp-block-paragraph">Attempting to solve heat problems by simply adding a cooler or enlarging the cooler just masks the symptom and prolongs the solution. Abnormal heat is a telegraphed S.O.S. call that commands attention and remediation.</p>



<p class="wp-block-paragraph">Critical temperatures on most high-speed and high-value machines are monitored in real time, often at multiple points, such as guide and thrust bearings (typically imbedded thermal couples). A common example of bearing temperature monitoring is shown in Figure 1.</p>



<p class="wp-block-paragraph">Here, a temperature excursion was noticed first before any other symptoms. After inspection, a lubrication issue (cake-lock) was found to be the root cause.</p>



<div class="wp-block-buttons is-layout-flex wp-block-buttons-is-layout-flex">
<div class="wp-block-button is-style-tesibis-outline-blue-blue"><a class="wp-block-button__link wp-element-button" href="https://www.machinerylubrication.com/Read/31381/heat-contaminant-symptom" target="_blank" rel="noreferrer noopener">Read the full article</a></div>
</div>
<p>The post <a href="https://tesibis.com/rca-and-failure-analysis/2-be-alert-to-heat-as-both-a-contaminant-and-a-symptom/">Be Alert to Heat as Both a Contaminant and a Symptom</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
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		<title>Grease Dry-out: Causes, Effects and Remedies</title>
		<link>https://tesibis.com/grease-lubrication/2-grease-dry-out-causes-effects-and-remedies/</link>
		
		<dc:creator><![CDATA[Jim Fitch]]></dc:creator>
		<pubDate>Wed, 24 Dec 2025 00:19:49 +0000</pubDate>
				<category><![CDATA[Grease Lubrication]]></category>
		<category><![CDATA[base oil oxidation]]></category>
		<category><![CDATA[cake-lock]]></category>
		<category><![CDATA[contamination]]></category>
		<category><![CDATA[incompatible grease]]></category>
		<category><![CDATA[thermal degradation]]></category>
		<category><![CDATA[volatility]]></category>
		<guid isPermaLink="false">https://tesibis.com/?p=1420</guid>

					<description><![CDATA[<p>One of the main disadvantages of using grease over oil is the annoying tendency of grease to cake and dry out. We all know that oil has a natural tendency to drain out of the grease thickener over time.</p>
<p>The post <a href="https://tesibis.com/grease-lubrication/2-grease-dry-out-causes-effects-and-remedies/">Grease Dry-out: Causes, Effects and Remedies</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
]]></description>
										<content:encoded><![CDATA[
<p class="wp-block-paragraph">By Jim Fitch<br>Machinery Lubrication Magazine</p>



<figure class="wp-block-image size-full"><img loading="lazy" decoding="async" width="500" height="375" src="https://tesibis.com/wp-content/uploads/2025/12/image-199.png" alt="" class="wp-image-1421" srcset="https://tesibis.com/wp-content/uploads/2025/12/image-199.png 500w, https://tesibis.com/wp-content/uploads/2025/12/image-199-300x225.png 300w" sizes="auto, (max-width: 500px) 100vw, 500px" /></figure>



<p class="wp-block-paragraph">One of the main disadvantages of using grease over oil is the annoying tendency of grease to cake and dry out. We all know that oil has a natural tendency to drain out of the grease thickener over time. We see conspicuous evidence of this when oil puddles in unleveled grease pockets in pails of new grease. We’ve also seen the dribble of oil from stored grease cartridges and prepacked bearings on storeroom shelves.</p>



<p class="wp-block-paragraph">More serious is the hardened byproduct of oil drainage that builds inside the cavities of operating bearings and gears over time. Often this takes years to develop, while in other cases the condition can reach catastrophic levels in just a few weeks. The failure can be self-propagating. As grease becomes dry, frictional forces escalate, causing concentrated heat within the bearing.</p>



<p class="wp-block-paragraph">The elevated heat continues to force more rapid and complete drying of the grease. In time, the grease can reach a state of consistency ranging from hard putty to sandstone, depending on the thickener type and degradation conditions.</p>



<p class="wp-block-paragraph">Frequently the most serious offending conditions leading to grease dry-out are aided by other causes working in concert. Let’s begin by reviewing the primary causes of grease dry-out. Once the causes are determined, we have the information necessary to prescribe steps to grease your bearings properly.</p>



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<div class="wp-block-button is-style-tesibis-outline-blue-blue"><a class="wp-block-button__link wp-element-button" href="https://www.machinerylubrication.com/Read/28517/grease-dry-out-causes" target="_blank" rel="noreferrer noopener">Read the full article</a></div>
</div>
<p>The post <a href="https://tesibis.com/grease-lubrication/2-grease-dry-out-causes-effects-and-remedies/">Grease Dry-out: Causes, Effects and Remedies</a> appeared first on <a href="https://tesibis.com">Tesibis</a>.</p>
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